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- Name help_outline geranylgeranyl diphosphate Identifier CHEBI:57533 Charge -3 Formula C20H33O7P2 InChIKeyhelp_outline OINNEUNVOZHBOX-UHFFFAOYSA-K SMILEShelp_outline CC(C)=CCCC(C)=CCCC(C)=CCCC(C)=CCOP([O-])(=O)OP([O-])([O-])=O 2D coordinates Mol file for the small molecule Search links Involved in 74 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
- Name help_outline β-araneosene Identifier CHEBI:193074 Charge 0 Formula C20H32 InChIKeyhelp_outline VSEDLQDFSQWMRG-WSHNDMGWSA-N SMILEShelp_outline C1C[C@@]2([C@@](C1=C(C)C)(CCC(=CCCC(=CC2)C)C)[H])C 2D coordinates Mol file for the small molecule Search links Involved in 1 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
- Name help_outline diphosphate Identifier CHEBI:33019 (Beilstein: 185088) help_outline Charge -3 Formula HO7P2 InChIKeyhelp_outline XPPKVPWEQAFLFU-UHFFFAOYSA-K SMILEShelp_outline OP([O-])(=O)OP([O-])([O-])=O 2D coordinates Mol file for the small molecule Search links Involved in 1,146 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
Cross-references
| RHEA:73991 | RHEA:73992 | RHEA:73993 | RHEA:73994 | |
|---|---|---|---|---|
| Reaction direction help_outline | undefined | left-to-right | right-to-left | bidirectional |
| UniProtKB help_outline |
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Publications
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Characterisation of three terpene synthases for beta-barbatene, beta-araneosene and nephthenol from social amoebae.
Rinkel J., Koellner T.G., Chen F., Dickschat J.S.
The products of three terpene synthases from two social amoebae, Dictyostelium discoideum and Dictyostelium purpureum, were identified, showing sesquiterpene synthase activity for one and diterpene synthase activity for the other two enzymes. Site-directed mutagenesis experiments revealed the impo ... >> More
The products of three terpene synthases from two social amoebae, Dictyostelium discoideum and Dictyostelium purpureum, were identified, showing sesquiterpene synthase activity for one and diterpene synthase activity for the other two enzymes. Site-directed mutagenesis experiments revealed the importance of a newly identfied highly conserved residue for catalytic activity. For one of the enzyme products, β-araneosene, a bromonium ion induced transannular cyclisation was investigated, yielding the first brominated derivatives of this diterpene. << Less
Chem. Commun. (Camb.) 55:13255-13258(2019) [PubMed] [EuropePMC]
This publication is cited by 2 other entries.