Reaction participants Show >> << Hide
- Name help_outline (Z)-(2R)-2-hydroxy-3-butenyl-N-(sulfonatooxy)methanimidothioate Identifier CHEBI:183097 Charge -2 Formula C5H7NO5S2 InChIKeyhelp_outline AVNALOICIMCLQH-BYPYZUCNSA-L SMILEShelp_outline [S-]/C(=N\OS([O-])(=O)=O)/C[C@H](C=C)O 2D coordinates Mol file for the small molecule Search links Involved in 4 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
- Name help_outline 3-hydroxypent-4-ene nitrile Identifier CHEBI:183221 Charge 0 Formula C5H7NO InChIKeyhelp_outline PBCLOVRWBLGJQA-YFKPBYRVSA-N SMILEShelp_outline C(C[C@H](C=C)O)#N 2D coordinates Mol file for the small molecule Search links Involved in 1 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
- Name help_outline sulfate Identifier CHEBI:16189 (Beilstein: 3648446; CAS: 14808-79-8) help_outline Charge -2 Formula O4S InChIKeyhelp_outline QAOWNCQODCNURD-UHFFFAOYSA-L SMILEShelp_outline [O-]S([O-])(=O)=O 2D coordinates Mol file for the small molecule Search links Involved in 91 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
- Name help_outline sulfur Identifier CHEBI:26833 (CAS: 7704-34-9) help_outline Charge 0 Formula S InChIKeyhelp_outline NINIDFKCEFEMDL-UHFFFAOYSA-N SMILEShelp_outline [S] 2D coordinates Mol file for the small molecule Search links Involved in 16 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
Cross-references
| RHEA:69296 | RHEA:69297 | RHEA:69298 | RHEA:69299 | |
|---|---|---|---|---|
| Reaction direction help_outline | undefined | left-to-right | right-to-left | bidirectional |
| UniProtKB help_outline |
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Related reactions help_outline
More general form(s) of this reaction
Publications
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Characterisation of recombinant epithiospecifier protein and its over-expression in Arabidopsis thaliana.
de Torres-Zabala M., Grant M., Bones A.M., Bennett R., Lim Y.S., Kissen R., Rossiter J.T.
Epithiospecifier protein (ESP) is a protein that catalyses formation of epithionitriles during glucosinolate hydrolysis. In vitro assays with a recombinant ESP showed that the formation of epithionitriles from alkenylglucosinolates is ESP and ferrous ion dependent. Nitrile formation in vitro howev ... >> More
Epithiospecifier protein (ESP) is a protein that catalyses formation of epithionitriles during glucosinolate hydrolysis. In vitro assays with a recombinant ESP showed that the formation of epithionitriles from alkenylglucosinolates is ESP and ferrous ion dependent. Nitrile formation in vitro however does not require ESP but only the presence of Fe(II) and myrosinase. Ectopic expression of ESP in Arabidopsis thaliana Col-5 under control of the strong viral CaMV 35S promoter altered the glucosinolate product profile from isothiocyanates towards the corresponding nitriles. << Less
Phytochemistry 66:859-867(2005) [PubMed] [EuropePMC]
This publication is cited by 7 other entries.