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- Name help_outline styrene oxide Identifier CHEBI:17907 (Beilstein: 108582; CAS: 96-09-3) help_outline Charge 0 Formula C8H8O InChIKeyhelp_outline AWMVMTVKBNGEAK-UHFFFAOYSA-N SMILEShelp_outline C1OC1c1ccccc1 2D coordinates Mol file for the small molecule Search links Involved in 2 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
- Name help_outline 2-phenylacetaldehyde Identifier CHEBI:16424 (Beilstein: 385791; CAS: 122-78-1) help_outline Charge 0 Formula C8H8O InChIKeyhelp_outline DTUQWGWMVIHBKE-UHFFFAOYSA-N SMILEShelp_outline [H]C(=O)Cc1ccccc1 2D coordinates Mol file for the small molecule Search links Involved in 11 reaction(s) Find molecules that contain or resemble this structure Find proteins in UniProtKB for this molecule
Cross-references
| RHEA:21604 | RHEA:21605 | RHEA:21606 | RHEA:21607 | |
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| Reaction direction help_outline | undefined | left-to-right | right-to-left | bidirectional |
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Publications
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Metabolism of Styrene Oxide and 2-Phenylethanol in the Styrene-Degrading Xanthobacter Strain 124X.
Hartmans S., Smits J.P., van der Werf M.J., Volkering F., de Bont J.A.
Styrene oxide and 2-phenylethanol metabolism in the styrene-degrading Xanthobacter sp. strain 124X was shown to proceed via phenylacetaldehyde and phenylacetic acid. In cell extracts 2-phenylethanol was oxidized by a phenazine methosulfate-dependent enzyme, probably a pyrroloquinoline quinone enzy ... >> More
Styrene oxide and 2-phenylethanol metabolism in the styrene-degrading Xanthobacter sp. strain 124X was shown to proceed via phenylacetaldehyde and phenylacetic acid. In cell extracts 2-phenylethanol was oxidized by a phenazine methosulfate-dependent enzyme, probably a pyrroloquinoline quinone enzyme. Xanthobacter sp. strain 124X also contains a novel enzymatic activity designated as styrene oxide isomerase. Styrene oxide isomerase catalyzes the isomerization of styrene oxide to phenylacetaldehyde. The enzyme was partially purified and shown to have a very high substrate specificity. Of the epoxides tested, styrene oxide was the only substrate transformed. The initial step in styrene metabolism in Xanthobacter sp. strain 124X is oxygen dependent and probably involves oxidation of the aromatic nucleus. << Less
Appl Environ Microbiol 55:2850-2855(1989) [PubMed] [EuropePMC]